The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Organics (N-compounds) / Peroxynitrates / FC(O)OONO2 / Malanca(2006)_273K_200-320nm

DATAFILE: FC(O)OONO2_Malanca(2006)_273K_200-320nm.txt
NAME: fluorocarbonyl peroxynitrate
FORMULA: FC(O)OONO2
AUTHOR(YEAR): Malanca(2006)
T: 273K
λ: 200-320nm
BIBLIOGRAPHY: F.E. Malanca, M.S. Chiappero, and G.A. Argüello, "Fluorocarbonyl peroxynitrate (FC(O)OONO2). Temperature dependence of the UV absorption spectrum", J. Photochem Photobiol. A: Chem. 184, 212-215 (2006); DOI: 10.1016/j.jphotochem.2006.04.017
COMMENTS: Averages over 5-nm intervals of the spectrum recorded at a resolution of 1 nm using a diode array spectrometer

The representation of log σ vs. T leads to linear fits according to

log10 σ(T) = B × T + log10 σ(0 K).

The intercepts σ(0 K) and slopes B at selected wavelengths are as follows (standard deviations in brackets):

-----------------------------------------------------
λ   103 B   1020 σ(0 K)
(nm) (K-1)   (cm2 molecule-1)
-----------------------------------------------------
260 1.5 (0.1)  2.4 (0.2)
270 2.0 (0.2)  0.85 (0.08)
280 1.5 (0.3)  0.48 (0.05)
290 4.0 (0.3)  0.45 (0.005)
300 6.8 (0.4)  0.004 (0.002)

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